Interfacial self-assembly of water-soluble cationic porphyrins for the reduction of oxygen to water.
نویسندگان
چکیده
Meet at the border: Assembly of the water-soluble cobalt tetrakis(N-methylpyridinium-4-yl)porphyrin [CoTMPyP](4+) at soft interfaces is enhanced and stabilized by its interfacial interaction with the lipophilic anion (C(6)F(5))(4)B(-). The supramolecular structure thus formed provides excellent catalytic activity in the four-electron reduction of oxygen.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 51 26 شماره
صفحات -
تاریخ انتشار 2012